Product ID:QUROX, 0373
MSDS Date:11/11/1987
FSC:6850
NIIN:01-433-6442
MSDS Number: CKLLR

CERTIFIED LABS DIV OF NCH CORP

IRVING, TX 75015
US

Emergency Phone: 214-438-1381

Info Phone: 214-438-1381

Preparer: RICHARD STOLLEY

Cage: 53417

CERTIFIED LABS DIV OF NCH CORP

152170 IRVING, TX 75015 US

Telephone: 214-438-1381972-438-1381

Cage: 53417

TANNIC ACIDS

CAS: 1401-55-4

RTECS: FM3015000

OXALIC ACID

CAS: 144-62-7

RTECS: RO2450000

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3

LD50 LC50 Mixture:ORAL LD50(RAT): 2300 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION: MIST SITUATION MAY
CAUSE IRRITATION TO RESPIRATORY TRACT. MAY CAUSE COUGHING AND
SNEEZING. SKIN: MAY CAUSE MILD IRRITATION. CONTACT WITH OPEN WOUNDS
CAN PROMOTE ABSORBTION AND SYSTE MIC EFFECTS. IN AUTOPSIED BURNED
VICTIMS. OBSERVED LIVER DAMAGE WAS ATTRIBUTED TO ABSORBTION OF
TANNIC ACID THROUGH BURNED SKIN. EYE: MAY CAUSE REDDENING AND
TEARING WITH POSSIBLE PAIN AND BLURRED VIS ION. INGESTION: TOXIC
MAY CAUSE GASTROINTESTINAL DISORDERS INCLUDING NAUSEA AND
VOMITING. MASSIVE INGESTION CAN CAUSE SHOCK AND COLLAPSE. CHRONIC:
MARKED IRRITATION TO SKIN AND EYES. SHOW EVIDENCE OF GASTRITIS AND
LIVER DAMAGE.
Explanation of Carcinogenicity:NO
Effects of Overexposure:ACUTE: INHALATION: MIST SITUATION MAY CAUSE
IRRITATION TO RESPIRATORY TRACT. MAY CAUSE COUGHING AND SNEEZING.
SKIN: MAY CAUSE MILD IRRITATION. CONTACT WITH OPEN WOUNDS CAN
PROMOTE ABSORBTION AND SYSTE MIC EFFECTS. IN AUTOPSIED BURNED
VICTIMS. OBSERVED LIVER DAMAGE WAS ATTRIBUTED TO ABSORBTION OF
TANNIC ACID THROUGH BURNED SKIN. EYE: MAY CAUSE REDDENING AND
TEARING WITH POSSIBLE PAIN AND BLURRED VIS ION. INGESTION: TOXIC
MAY CAUSE GASTROINTESTINAL DISORDERS INCLUDING NAUSEA AND
VOMITING. MASSIVE INGESTION CAN CAUSE SHOCK AND COLLAPSE. CHRONIC:
MARKED IRRITATION TO SKIN AND EYES. SHOW EVIDENCE OF GASTRITIS AND
LIVER DAMAGE.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN OR
EYE DISORDERS OR IMPAIRED KIDNEY, LIVER AND RESPIRATORY FUNCTION
MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE.

First Aid:INHALATION-GET TO FRESH AIR AND TREAT SYMPTOMATICALLY. IF
BREATHING IS LABORED, GIVE OXYGEN OR ARTIFICIAL RESPIRATION. SEE A
PHYSICIAN IF SYMPTOMS OCCUR. EYE-FLUSH WITH LARGE AMOUNTS OF WATER
FOR 10 M INUTES LIFTING UPPER AND LOWER LIDS OCCASIONALLY. GET
MEDICAL ATTENTION IMMEDIATELY. TREATMENT IS MOST EFFECTIVE WITHIN
ONE MIN. SKIN:THOROUGHLY WASH EXPOSED AREA WITH SOAP AND WATER.
REMOVE CONTAMINA TED CLOTHING. LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. APPLY EMOLLIENT RICH CREAM. INGESTION: GIVE TWO GLASSES OF
WATER TO DILUTE CONTENTS OF STOMACH. DO NOT INDUCE VOMITING. SEE A
PHYSICIAN AT ONC E.

Flash Point:NON-FLAMMABLE
Extinguishing Media:ALCOHOL, FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER
SPRAY.
Fire Fighting Procedures:ALTHOUGH PRODUCT IS NON-FLAMMABLE, TREAT AS
ANY CHEMICAL FIRE. WEAR A SELF-CONTAINED BREATHING APPARATUS AND
FULL PROTECTIVE GEAR TO AVOID EXPOSURE TO POSSIBLE HAZARDOUS
COMBUSTION PRODUCTS.
Unusual Fire/Explosion Hazard:SPRAY EXPOSED CONTAINERS WITH WATER SPRAY
TO AVOID STEAM PRODUCTION.

Spill Release Procedures:CONTAIN LEAK AND PICK UP SPILL AND PLACE IN A
LABELED CONTAINER. CLEAN UP RESIDUE WITH DETERGENT AND WATER. ADD
CAUTIOUSLY A SOLUTION OF SLAKED LIME OR SODA ASH WHILE STIRRING
UNTIL PH IS AT 7.
Neutralizing Agent:SLAKED LIME OR SODA ASH.

Handling and Storage Precautions:STORAGE TEMPERATURE: 120F MAX. AND 35F
MINIMUM. INDOOR. KEEP DRUM TIGHTLY CLOSED. KEEP OUT OF REACH OF
CHILDREN. READ ENTIRE LABEL BEFORE USING PRODUCT.
Other Precautions:NOTES TO PHYSICIAN: ADDITION OF BASIC NEUTRALIZER IS
NOT RECOMMENDED DUE TO ALKALI SALTS OF OXALIC ACID ARE JUST AS
TOXIC AS ACIDIC FORM.

Respiratory Protection:A RESPIRATOR IS NOT REQUIRED IN THE NORMAL USE
OF THE PRODUCT. USE A NIOSH APPROVED MASK FOR SPRAY MISTS.
Ventilation:GENERAL EXHAUST IS MORE THAN ADEQUATE TO PROTECT WORKER
FROM EXPOSURE TO LEVELS ABOVE PERMISSIBLE EXPOSURE LIMITS.
Protective Gloves:NEOPRENE OR NITRILE RUBBER GLOVES SHOULD BE WORN.
Eye Protection:CHEMICAL GOGGLES SHOULD BE WORN DEPENDING ON SEVERITY OF
EXPOSURE.
Other Protective Equipment:APRON SHOULD BE WORN DEPENDING ON SEVERITY
OF EXPOSURE.
Supplemental Safety and Health

HCC:C1
Boiling Pt:=101.7C, 215.F
Vapor Pres:18 (MMHG)
Vapor Density:0.6
Spec Gravity:1.180
pH:1-2
Viscosity:SLIGHT-VISCOUS.
Evaporation Rate & Reference:0.1 (BUTYL ACETATE=1)
Solubility in Water:COMPLETE.
Appearance and Odor:TAN COLOR, LATEX ODOR.
Percent Volatiles by Volume:42 WT

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS (BLEACH), SILVER AND ALKALIS.
Stability Condition to Avoid:KEEP CONTAINER TIGHTLY CLOSED.
Hazardous Decomposition Products:CARBON MONOXIDE, ACRID SMOKE AND
FUMES.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Toxicological Information:TANNIC ACID: ORL-RAT LDLO: 2000MG/KG. ORL-RBT
LD50: 5000MG/KG. SCU-RAT TDLO: 4450MG/KG/17ORL-RAT LD50: 2300MG/KG.
ORL-RBT LD50: 5000MG/KG. OXALIC ACID: ORL0HMN LDLO: 71MG/KG.
ORL-RAT LD50: 375MG/KG. S KN-RBT: 500MG/24H MOD.